This is expected to happen just before sunset, between 5:30 PM and 6:30 PM.
The weather forecast right now from the National Weather Service calls for Sunny skies [[granted, there's never a guarantee with that in the Great Lakes region during October), so it appears most folks will be able to see it.
http://forecast.weather.gov/MapClick...1#.VEapW_nF9dg
http://www.timeanddate.com/eclipse/in/usa/detroit
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